Concepedia

An Asymmetric Synthesis of Both Enantiomers of the Indole Alkaloid Deplancheine

Steven M. Allin, Christopher I. Thomas, Kevin Doyle, M.R.J. Elsegood

The Journal of Organic Chemistry · 2004 · 60 citations · 10 references

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Abstract

We report a novel, facile and asymmetric approach to both enantiomers of the indole alkaloid deplancheine from a readily available, nonracemic chiral template. The natural product and its antipode are isolated with >95% ee.

References

10

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Synthesis of Chiral Azacrown Ethers Derived from a-D-Glucose and Their Catalytic Properties on the Asymmetric Michael Addition

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Stereocontrolled synthesis of exocyclic trisubstituted double bonds by stereospecific iminium ion-vinylsilane cyclizations. A short synthetic route to indoloquinolizidine alkaloids

Larry E. Overman, Thomas C. Malone · The Journal of Organic Chemistry · 1982 · 39 citations

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