Concepedia

Modulating the electrical conductivity of metal–organic framework films with intercalated guest π-systems

Zhiyong Guo, Dillip K. Panda, Krishnendu Maity, David Hobbs Lindsey, T. Gannon Parker, Thomas E. Albrecht‐Schmitt, Jorge L. Barreda-Esparza, Peng Xiong, Wei Zhou, Sourav Saha

Journal of Materials Chemistry C · 2015 · 92 citations · 42 references

DOI

Concepts

Abstract

The formation of guest-mediated π-donor/acceptor stacks within electroactive metal–organic frameworks activates long-range charge mobilization, boosting the electrical conductivity of the doped materials.

References

42

The Chemistry and Applications of Metal-Organic Frameworks

Hiroyasu Furukawa, Kyle E. Cordova, M. O’Keeffe et al. · Science · 2013 · 16.5K citations

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Porous materials with optimal adsorption thermodynamics and kinetics for CO2 separation

Patrick Nugent, Youssef Belmabkhout, Stephen Burd et al. · Nature · 2013 · 2.3K citations

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Rethinking the term “pi-stacking”

Chelsea R. Martinez, Brent L. Iverson · Chemical Science · 2012 · 1.6K citations · Full text

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Tunable Electrical Conductivity in Metal-Organic Framework Thin-Film Devices

A. Alec Talin, Andrea Centrone, Alexandra C. Ford et al. · Science · 2013 · 1.2K citations · Full text

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High Electrical Conductivity in Ni<sub>3</sub>(2,3,6,7,10,11-hexaiminotriphenylene)<sub>2</sub>, a Semiconducting Metal–Organic Graphene Analogue

Dennis Sheberla, Lei Sun, Martin A. Blood-Forsythe et al. · Journal of the American Chemical Society · 2014 · 1.1K citations · Full text

, , +16