Publication | Closed Access
The Determination of Carbonyl Compounds in Ozonated Water by the PFBOA Method
81
Citations
8
References
1989
Year
Advanced Oxidation ProcessEngineeringMarine ChemistryOrganic ChemistryChemistryWastewater TreatmentOrganic GeochemistryEnvironmental ChemistryChemical EngineeringCarbonyl CompoundsCarbonyl Ozonation By-productsEnvironmental Analytical ChemistryWater TreatmentAnalytical ChemistryDrinking Water TreatmentChromatographyChemical MeasurementOzonated WaterWater QualityEcotoxicologyChemical PollutionWater AnalysisPfboa MethodAbstract PfboaEnvironmental EngineeringPfboa DerivativesWater PurificationActivated CarbonMedicineDrug Analysis
Abstract PFBOA, O-(2,3,4,5,6-pentafluorobenzyl)hydroxylamine, is excellent as a derivatizing agent in the GC determination of carbonyl compounds in ozonated water samples. Surface and waste waters have been ozonated. The carbonyl ozonation by-products were identified as PFBOA derivatives by gas chromatography-mass spectrometry. The main by-products of ozonation identified were formaldehyde, glyoxal, methylglyoxal, and 13 other compounds. The characteristics of the first three compounds with respect to production and decomposition during ozonation are discussed.
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