Concepedia

The catalytic asymmetric aldol reaction of silyl ketene acetals with aldehydes in the presence of a chiral borane complex. Nitroethane as a highly effective solvent for catalytic conditions

Syun‐ichi Kiyooka, Yuichi Kaneko, Ken-ichi Kume

Tetrahedron Letters · 1992 · 118 citations · 14 references

DOI

Concepts

References

14

Development and use of quantum mechanical molecular models. 76. AM1: a new general purpose quantum mechanical molecular model

Michael J. S. Dewar, Eve G. Zoebisch, Eamonn F. Healy et al. · Journal of the American Chemical Society · 1985 · 13.1K citations

, , +10

Chiral Lewis Acids in Catalytic Asymmetric Reactions

Koichi Narasaka · Synthesis · 1991 · 278 citations

, , +15

First application of attractive intramolecular interactions to the design of chiral catalysts for highly enantioselective Diels-Alder reactions

E. J. Corey, Teck‐Peng Loh · Journal of the American Chemical Society · 1991 · 275 citations

, , +14

Asymmetric aldol reaction between achiral silyl enol ethers and achiral aldehydes by use of a chiral promoter system

Shū Kobayashi, Hiromi Uchiro, Yuko Fujishita et al. · Journal of the American Chemical Society · 1991 · 225 citations

, , +10

Stereoselective aldol condensation. Use of chiral boron enolates

Satoru Masamune, William Choy, Kerdesky Francis A. J. et al. · Journal of the American Chemical Society · 1981 · 212 citations

, , +8