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Mechanism of phase-transfer catalysis
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1977
Year
Organic CationCatalytic MembraneChemical EngineeringMembrane FormationEngineeringMembrane TransportPhase-transfer CatalysisHeterogeneous CatalysisOrganic ChemistryCatalysisHomogeneous CatalysisChemistryMembrane PermeationKinetic MeasurementsMolecular Catalysis
Using liquid membranes it was shown that in phase-transfer catalysis the transport of anions from one phase into the other does not require the concomitant transfer of the organic cation; kinetic measurements indicate that the effectiveness of the catalyst depends essentially on its organophilicity.