Synthesis of Monodisperse Spherical Nanocrystals

TLDR

Monodisperse spherical nanocrystals of metals, metal oxides, and chalcogenides have been synthesized by various methods—including high‑temperature nucleation, thermal decomposition, sol‑gel, and digestive‑ripening—with size control achieved through burst nucleation and diffusion‑controlled growth. Polyol processes reduce metal salts with alcohols in the presence of surfactants to produce uniform‑size gold, silver, platinum, and palladium nanocrystals.

Abstract

Much progress has been made over the past ten years on the synthesis of monodisperse spherical nanocrystals. Mechanistic studies have shown that monodisperse nanocrystals are produced when the burst of nucleation that enables separation of the nucleation and growth processes is combined with the subsequent diffusion-controlled growth process through which the crystal size is determined. Several chemical methods have been used to synthesize uniform nanocrystals of metals, metal oxides, and metal chalcogenides. Monodisperse nanocrystals of CdSe, Co, and other materials have been generated in surfactant solution by nucleation induced at high temperature, and subsequent aging and size selection. Monodisperse nanocrystals of many metals and metal oxides, including magnetic ferrites, have been synthesized directly by thermal decomposition of metal-surfactant complexes prepared from the metal precursors and surfactants. Nonhydrolytic sol-gel reactions have been used to synthesize various transition-metal-oxide nanocrystals. Monodisperse gold nanocrystals have been obtained from polydisperse samples by digestive-ripening processes. Uniform-sized nanocrystals of gold, silver, platinum, and palladium have been synthesized by polyol processes in which metal salts are reduced by alcohols in the presence of appropriate surfactants.