Publication | Closed Access
Total Syntheses of Doubly Locked Biliverdin Derivatives toward Elucidation of the Stereochemistry of Phytochrome Chromophore
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Citations
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2008
Year
Bioorganic ChemistryEngineeringOrganic ChemistryFree Acid FormsChemistryDifferent TypesTotal SynthesesPhototropinStereoselective SynthesisPhotochemistryBiochemistryPhytochrome ChromophoreNatural Product SynthesisPhotochromismBiomolecular EngineeringNatural SciencesMolecular SwitchPhytochromePhytochemistrySynthetic Chemistry
Abstract To elucidate the stereochemistry of phytochrome chromophore in far-red light absorbing form (Pfr), four different types of doubly locked biliverdin (BV) derivatives, 5Zs15Ea-BV, 5Za15Ea-BV, 5Es15Ea-BV, and 5Ea15Ea-BV, were synthesized for the first time in free acid forms.
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