Reactions of Diaryldibromodisilenes with N‐Heterocyclic Carbenes: Formation of Formal Bis‐NHC Adducts of Silyliumylidene Cations

Abstract

Reactions of stable 1,2-dibromodisilenes ((E)-Ar(Br)Si=Si(Br)Ar) with N-heterocyclic carbenes (NHC) afforded NHC-arylbromosilylene adducts or bromide salts of the corresponding bis-NHC adducts of the formal arylsilyliumylidene cations ([ArSi:](+)). In some cases, an NHC was able to replace a bromide anion in the coordination sphere of the arylbromosilylene-NHC adduct.