Journal of the Chemical Society Chemical Communications · 1987 · 89 citations · 0 references
Natural SciencesChemistryInorganic ChemistryOrganometallic ChemistrySolid-state ChemistryCoordination ChemistryTransition Metal ChemistryTransition Metal ComplexesElectrochemical OxidationPlatinum CompoundsPyramidal System
The complex cation [Pt(1)2]2+[(1)= 1,4,7-trithiacyclononane] shows a quasi square based pyramidal structure with one non-bonding sulphur donor atom; electrochemical oxidation at +0.5 V. vs. Fc0/Fc+(Fc = ferrocene) at 20 °C in MeCN affords a paramagnetic platinum(III) species.