Concepedia

Oxaphosphole‐Based Monophosphorus Ligands for Palladium‐Catalyzed Amination Reactions

Sonia Rodrı́guez, Bo Qu, Nizar Haddad, Diana C. Reeves, Wenjun Tang, Heewon Lee, Dhileepkumar Krishnamurthy, Chris H. Senanayake

Advanced Synthesis & Catalysis · 2011 · 64 citations · 40 references

DOI

Concepts

Abstract

Abstract A novel class of C‐2‐substituted oxaphosphole‐based monophosphines 1–4 has been synthesized. Palladium complexes derived from these ligands and their C‐2‐unsubstituted analogs provide general catalysts for amination reactions of challenging aryl and heteroaryl halides with sterically hindered anilines and alkylamines.

References

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