Controlled Reducibility of a Metal–Organic Framework with Coordinatively Unsaturated Sites for Preferential Gas Sorption

Abstract

Gas grabber: Reduction of the porous metal–organic framework MIL-100(Fe) (see picture; X−: OH− or F−; red: O of trimesate ligands) to form coordinatively unsaturated sites at iron(II) (depicted as a violet circle) is essential for selective gas purification or the selective removal of unsaturated gas impurities. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.