Formation of [60]Fullerene Nanoclusters with Controlled Size and Morphology through the Aid of Supramolecular Rod–Coil Diblock Copolymers

Abstract

On the starting block: Polystyrene-block-poly(4-vinylpyridine) and a [60]fullerene carboxylic acid combine to form spherical supramolecular aggregates (see picture), the size and morphology of which can be controlled by changing the block composition ratio in the copolymer. The method is generally applicable to the construction of organic nanoparticles. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2005/z461174_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.