Concepedia

The First Structurally Characterized Aluminum Compounds with Terminal Acetylide Groups

Wenjun Zheng, Nadia C. Mösch‐Zanetti, Herbert W. Roesky, M. Hewitt, Fanica Cimpoesu, T. Schneider, Andreas Stasch, J. Prust

Angewandte Chemie International Edition · 2000 · 42 citations · 20 references

DOI

Concepts

Abstract

A twisted six-membered Al2N4 ring, which is rationalized by ab initio calculations, is present in compound 1. This compound together with 2 is obtained from the reaction of acetylenes with an aluminum dihydride bearing pyrazolato ligands. Compounds 1 and 2 are the first structurally characterized aluminum compounds with terminal acetylide groups.

References

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