Concepedia

Indium-Catalyzed Addition of Active Methylene Compounds to 1-Alkynes

Masaharu Nakamura, Kohei Endo, Eiichi Nakamura

Journal of the American Chemical Society · 2003 · 140 citations · 4 references

DOI

Concepts

Abstract

An active methylene compound adds to a 1-alkyne in high to quantitative yield upon heating in the presence of 0.05-5 mol % of In(OTf)3 to give an alpha-alkenylated carbonyl compound.

References

4

The mechanism of the zirconium-catalyzed carbomagnesiation reaction. Efficient and selective catalytic carbomagnesiation with higher alkyls of magnesium

Amir H. Hoveyda, James P. Morken, Ahmad Houri et al. · Journal of the American Chemical Society · 1992 · 85 citations

, , +5

Catalytic Radical Addition of Carbonyl Compounds to Alkenes by Mn(II)/Co(II)/O<sub>2</sub> System

Kouji Hirase, Takahiro Iwahama, Satoshi Sakaguchi et al. · The Journal of Organic Chemistry · 2002 · 70 citations

, , +10

Addition of Azaenolates to Simple, Unactivated Olefins

Katsumi Kubota, Eiichi Nakamura · Angewandte Chemie International Edition in English · 1997 · 61 citations

, , +3

Ligand‐Mediated Coupling of Organometallic Reaction Centers

Wolfgang Kaim, Ralf Reinhardt, Jan Fiedler · Angewandte Chemie International Edition in English · 1997 · 44 citations

, , +14