Synthesis of Sulfondiimines by <i>N</i>‐Chlorosuccinimide‐Mediated Oxidative Imination of Sulfiliminium Salts

Abstract

Access to sulfondiimines: The oxidative one-pot chlorination–imination sequence of in situ generated free sulfilimines by N-chlorosuccinimide (NCS) allows the preparation of N-monosubstituted sulfondiimines under mild reaction conditions with excellent functional-group tolerance (see scheme; Mes=2,4,6-trimethylphenylsulfonyl) Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.