Angewandte Chemie International Edition · 2014 · 343 citations · 27 references
EngineeringMaterials EngineeringMaterials ScienceMembrane ScienceNanomaterialsTransport PhenomenaCarbon CaptureCarbon NanomaterialsGas Separation MembranesGraphene NanomaterialsMembrane FabricationMembrane MaterialsAdsorptive Gas SeparationCarbon-based MembranesDiffusion PathwaysGas Separation ProcessesGraphene MembranesGraphene OxideGraphene Oxide MembranesOperational Stability
Graphene oxide (GO) nanosheets were engineered to be assembled into laminar structures having fast and selective transport channels for gas separation. With molecular-sieving interlayer spaces and straight diffusion pathways, the GO laminates endowed as-prepared membranes with excellent preferential CO2 permeation performance (CO2 permeability: 100 Barrer, CO2/N2 selectivity: 91) and extraordinary operational stability (>6000 min), which are attractive for implementation of practical CO2 capture.
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