A Critical Size of Silicon Nano‐Anodes for Lithium Rechargeable Batteries

Abstract

Well-dispersed Si nanocrystals with sizes of approximately 5, 10, and 20 nm were prepared in reverse micelles at high pressure and 380 °C and investigated as anode materials for lithium batteries. The 10 nm sized nanocrystals show a first charge capacity y of 3380 mAh g−1 and the highest capacity retention of 81 % after 40 cycles, which can be increased to 96 % by carbon coating (see picture). Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.