Electroanalysis · 2009 · 157 citations · 33 references
Natural SciencesChemistryMaterials ScienceAnalytical ChemistryElectroanalytical MethodsElectrochemistryElectroanalytical ChemistryElectrochemical CellsElectrochemical DetectionElectrode MaterialsElectrode PotentialsWorking ElectrodesAntimony ChemistryBoron-doped Diamond ElectrodesElectrochemical Environmental SensingLinear RangeVoltammetric DetectionVoltammetric SensingVoltammetric SensorsVoltammetry
Abstract We report the simultaneous electroanalytical determination of Pb 2+ and Cd 2+ by linear sweep anodic stripping voltammetry (LSASV) using an antimony nanoparticle modified boron doped diamond (Sb‐BDD) electrode. Sb deposition was performed in situ with the analytes, from a solution of 1 mg L −1 SbCl 3 in 0.1 M HCl (pH 1). Pb 2+ inhibited the detection of Cd 2+ during simultaneous additions at the bare BDD electrode, whereas in the presence of antimony, both peaks were readily discernable and quantifiable over the linear range 50–500 μg L −1 .
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Antimony Film Electrode for Electrochemical Stripping Analysis
Samo B. Hočevar, Ivan Švancara, Božidar Ogorevc et al. · Analytical Chemistry · 2007 · 229 citations