Angewandte Chemie International Edition · 2015 · 348 citations · 25 references
Natural SciencesEnvironmental EngineeringMaterials ScienceEnvironmental RemediationMaterials ChemistrySurface ScienceHeavy Metal RemovalMetal SulfidesSensor MaterialsSoil PollutionSulfur ChemistrySulfur CompoundsFunctional CoatingsFunctional Surface CoatingsMercury PollutionMercury RemovalMercury SulfidesPolysulfide ChemistrySulfur Compound ChemistrySulfur Removal
A polysulfide material was synthesized by the direct reaction of sulfur and d-limonene, by-products of the petroleum and citrus industries, respectively. The resulting material was processed into functional coatings or molded into solid devices for the removal of palladium and mercury salts from water and soil. The binding of mercury(II) to the sulfur-limonene polysulfide resulted in a color change. These properties motivate application in next-generation environmental remediation and mercury sensing.
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