Concepedia

An Unusual Polyoxomolybdate: Giant Wheels Linked to Chains

Achim Müller, Erich Krickemeyer, Hartmut Bögge, Marc Schmidtmann, Frank Peters, Carsten Menke, Jochen Meyer

Angewandte Chemie International Edition in English · 1997 · 82 citations · 11 references

DOI

Concepts

Abstract

Rings containing 144 Mo atoms are linked by Mo-O-Mo bridges (depicted on the right) to form chains in the polyoxometalate presented here. The blue mixed-valent compound is formed by the reduction with iron powder of an acidified solution of polymolybdate in the presence of Na+ ions.

References

11

Polyoxometalate Chemistry: An Old Field with New Dimensions in Several Disciplines

Michael T. Pope, Achim Müller · Angewandte Chemie International Edition in English · 1991 · 3.6K citations

, , +16

Structural Inorganic Chemistry

Colin Eaborn · Journal of Organometallic Chemistry · 1985 · 2.8K citations

Synthesis of inorganic materials with complex form

Stephen Mann, Geoffrey A. Ozin · Nature · 1996 · 1.2K citations

, , +12

Supramolecular Inorganic Chemistry: Small Guests in Small and Large Hosts

Achim Müller, Hans Reuter, Stephan Dillinger · Angewandte Chemie International Edition in English · 1995 · 538 citations

, , +17

[Mo<sub>154</sub>(NO)<sub>14</sub>O<sub>420</sub>(OH)<sub>28</sub>(H<sub>2</sub>O)<sub>70</sub>]<sup>(25 ± 5)−</sup>: A Water‐Soluble Big Wheel with More than 700 Atoms and a Relative Molecular Mass of About 24000

Achim Müller, Erich Krickemeyer, Jochen Meyer et al. · Angewandte Chemie International Edition in English · 1995 · 381 citations

, , +12