Die Makromolekulare Chemie · 1961 · 17 citations · 4 references
Natural SciencesMaterials EngineeringMaterials ScienceMaterials CharacterizationMaterials ChemistryNanomaterialsElectron MicroscopyTransmission Electron MicroscopyCellulose MicrofibrilsCotton LintersMorphological UnitsUltrastructural Characterization
Abstract Cotton linters were hydrolyzed with 1 N HCI at 55°C. for 0.5–168 hours and beaten with ultra‐sound. Samples were investigated in the electron microscope and the microfibrillar fragments measured. The distribution curve shows a general maximum at about 500–600 Å, and several peaks standing out in a distance of about 100 Å. From this it is concluded that the elementary unit is 100 Å long, but there are also bigger units of 600 Å length, which are more resistant towards the hydrolytic attack. There is also a longer morphological unit of about 2500 Å length, which is in correspondence with earlier findings, but with the higher resolution of our electron microscope it could be shown that it consists of a bundle of microfibrillar fragments.
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The Fine Structure of Cellulose Microfibrils
A. Frey‐Wyssling · Science · 1954 · 211 citations
Effect of Cellulase on Cotton Fiber Microstructure
Blanche R. Porter, Jarrell H. Carra, Verne W. Tripp et al. · Textile Research Journal · 1960 · 13 citations