Beyond classical coordination: silver–π interactions in metal dipyrrin complexes

Domingo Salazar‐Mendoza, Stéphane A. Baudron, Mir Wais Hosseini

Chemical Communications · 2007 · 79 citations · 28 references

Concepts

Abstract

Homo- and hetero-leptic Zn and Cu complexes of dipyrrin type ligands bearing mono- and di-cyanophenyl groups when combined with silver cations lead to the formation of Ag(I)-C=C double bond interactions unprecedented in the crystalline phase.

References

28