Effect of periodic melting on geochemical and isotopic signals in an ice core from Lomonosovfonna, Svalbard

Abstract

We examine the quality of atmospherically deposited ion and isotope signals in an ice core taken from a periodically melting ice field, Lomonosovfonna in central Spitsbergen, Svalbard. The aim is to determine the degree to which the signals are altered by periodic melting of the ice. We use three diagnostics: (1) the relation between peak values in the ice chemical and isotopic record and ice facies type, (2) the number of apparent annual cycles in these records compared with independently determined number of years represented in the ice core, and (3) a statistical comparison of the isotopic record in the ice core and the isotope records from coastal stations from the same region. We find that during warm summers, as much as 50% of the annual accumulation may melt and percolate into the firn; in a median year this decreases to ∼25%. As a consequence of percolation, the most mobile acids show up to 50% higher concentrations in bubble‐poor ice facies compared with facies that are less affected by melt. Most of the other chemical species are less affected than the strong acids, and the stable water isotopes show little evidence of mobility. Annual or biannual cycles are detected in most parameters, and the water isotope record has a comparable statistical distribution to isotopic records from coastal stations. We conclude that ice cores from sites like Lomonosovfonna contain a useful environmental record, despite melt events and percolation and that most parameters preserve an annual, or in the worst cases, a biannual atmospheric signal.