Creation of Hollow Zeolite Architectures by Controlled Desilication of Al-Zoned ZSM-5 Crystals

Johan C. Groen, Torkel Bach, Ulrike Ziese, Anne M. Paulaime-van Donk, Krijn P. de Jong, Jacob A. Moulijn, Javier Pérez‐Ramírez

Journal of the American Chemical Society · 2005 · 498 citations · 9 references

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Abstract

Hollow zeolite architectures on different length scales have been obtained upon controlled desilication of Al-zoned ZSM-5 zeolites in alkaline medium. The hollow ZSM-5 crystals possess a functional Al-rich exterior and a tunable internal porosity and accessibility.

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