Angewandte Chemie International Edition · 2008 · 150 citations · 76 references
Natural SciencesBiochemistryChemistryBiocatalysisCatalysisOrganic ChemistryHeterocyclic ChemistryOrganic SynthesisBicyclononyne ChemistryRing-forming Reactions
Various linked unsaturated dicarbonyl compounds were cyclized by dienamine catalysis. Depending on the substrates, alternative pathways were observed, leading to mono- and bicyclic products in high enantiomeric excess.
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