Versatile Reactivity of Rhodium–Iminocarbenes Derived from <i>N</i>‐Sulfonyl Triazoles

Abstract

The migrations of different groups to the metal–carbene center of RhII-stabilized iminocarbenes that were derived from N-sulfonyl triazoles are discussed (see scheme). The reactivity of these Rh-iminocabenes can be tuned easily by variation of substituents on the parent triazole.