Concepedia

Ruthenium Complex‐Catalysed Heck Reactions of Areneboronic Acids; Mechanism, Synthesis and Halide Tolerance

Edward J. Farrington, Christopher F. J. Barnard, Elizabeth Rowsell, John M. Brown

Advanced Synthesis & Catalysis · 2005 · 33 citations · 43 references

DOI

Concepts

Abstract

Abstract Ruthenium‐arene complexes can act as efficient catalysts for the coupling of areneboronic acids with electrophilic alkenes. The chemoselectivity is completely different from palladium coupling, with full tolerance for halogen in the arene. NMR and ES‐MS studies have been carried out to elucidate the reaction pathway

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