Concepedia

Synthesis of an Optically Active Triorganostannyl Ketone

Marcel Gielen, Serge Simon

Bulletin des Sociétés Chimiques Belges · 1977 · 10 citations · 7 references

DOI

Concepts

Abstract

Abstract Racemic p‐(cyclohexylmethyl‐l‐naphthylstannyl) acetophenone (I) is transformed into its menthydrazone which is, after four recrystallizations, reconverted to optically active (I), [α] 20° 436 +0.25° ± 0.05°. Several methods have been used to determine the optical purity of optically active (I) without success.

References

7

Molecular asymmetry in the ferrocene series

J. Thomson · Tetrahedron Letters · 1959 · 58 citations

, , +11

A New Optically Active Reagent for Carbonyl Compounds; the Resolution of dl-Camphor

R. B. Woodward, T. P. Kohman, George C. Harris · Journal of the American Chemical Society · 1941 · 50 citations

, , +5

Synthesis of the First Optically Active Tetraorganotin Compound in Which the Tin Atom Is The Only Chiral Center

Marcel Gielen, Hassan Mokhtar-Jamaï · Bulletin des Sociétés Chimiques Belges · 1975 · 42 citations

, , +6

Configurational stability of asymmetrically substituted organotin compounds. An example of optical activity at the tin centre

Ugo Folli, Dario Iarossi, Fabio Taddei · Journal of the Chemical Society Perkin Transactions 2 · 1973 · 31 citations

, , +15

Investigations on organo‐tin compounds. XII. The action of lithium aluminium hydride and grignard reagents on organo‐tin nitriles and esters

G. J. M. Der Van Kerk, J. G. NOLTES · Journal of Applied Chemistry · 1959 · 18 citations

, , +5