Journal of the American Chemical Society · 2002 · 4.7K citations · 3 references
Natural SciencesChemistryMaterials ScienceInorganic ChemistryPolymer ChemistryCellulose BiochemistryCellulose ChemistryDissolution MediaIonic PolymersSolvent ExtractionCellulose DissolutionCellulose RegenerationCellulose SolubilityExtraction SolventsIonic Liquids
We report here initial results that demonstrate that cellulose can be dissolved without activation or pretreatment in, and regenerated from, 1-butyl-3-methylimidazolium chloride and other hydrophilic ionic liquids. This may enable the application of ionic liquids as alternatives to environmentally undesirable solvents currently used for dissolution of this important bioresource.
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Structural changes of cellulose dissolved in molten salt hydrates
Heike Leipner, Steffen Fischer, Erica Brendler et al. · Macromolecular Chemistry and Physics · 2000 · 122 citations