Concepedia

A stable zerovalent palladium chain enveloped by a π-electron sheath of conjugated polyene ligands

Yasuki Tatsumi, Tetsuro Murahashi, Mitsue Okada, Sensuke Ogoshi, Hideo Kurosawa

Chemical Communications · 2008 · 50 citations · 29 references

DOI

Concepts

Abstract

A surprisingly stable homoleptic Pd(0)(4) chain complex of non-activated olefins was isolated and structurally characterized by X-ray crystallographic analysis, and the unique structure and bonding are compared to those of the corresponding dicationic [Pd(4)](2+) chain sandwich complex.

References

29

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Ligand-free Heck reactions using low Pd-loading

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Tetsuro Murahashi, Masa‐aki Oka, Yasuhiro Hashimoto et al. · Science · 2006 · 197 citations

, , +16