IR spectra studies of core-shell type waterborne polyacrylate-polyurethane microemulsions

Abstract

The hydrogen bonds in films of the polyurethane and the core-shell type polyacrylate-polyurethane microemulsions have been studied by FTIR spectroscopy in the regions of NH absorption and CO absorption. The effects on hydrogen bonds of the composition, the core-shell ratio were revealed. At the same time, the relationship between the hydrogen bonds and the crosslinked structures (Type A and Type B) was discovered. The shifts of the NH and CO stretching bands to higher frequencies and the shift of NH bending bands to lower frequencies, with the increase of acetone CO number in the core, mean that the hydrogen bonds between the soft and hard segments, and those in the short-range order in the hard segment phase, are broken. The dipole/dipole interaction which is supposed to exist between the acetone CO groups in the core and the urethane CO in the shell can change the hydrogen bond distribution in the shell, and at the same time, lead to hydrogen bonds between acetone CO in the core and the urethane NH in the shell. Type A and B crosslinked structure between the core and the shell located at the interface of the core and the shell can confine the acetone CO within the crosslinking network, and Type B crosslinked structure also decreases the acetone CO numbers. These weaken the dipole/dipole interaction between the acetone CO and the urethane CO, and lead to the decrease of the effect of the acetone CO groups on the hydrogen bond distribution in the shell. © 1999 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 37: 2642–2650, 1999