Concepedia

Mixed Crystals Containing the Diamagnetic Complex [Mo<sub>2</sub>(SO<sub>2</sub>)(S<sub>2</sub>)(CN)<sub>8</sub>]<sup>4⊖</sup> and the Paramagnetic Complex [Mo<sub>2</sub>(SO<sub>2</sub>)(S<sub>2</sub>)(CN)<sub>8</sub>]<sup>5⊖</sup>

Achim Müller, Werner Eltzner, Rainer Jostes, Hartmut Bögge, E. Diemann, Jürgen Schimanski, Heiko Lueken

Angewandte Chemie International Edition in English · 1984 · 12 citations · 2 references

DOI

Concepts

Abstract

Blackish violet crystals of the mixed valence Mo compound 1 were obtained on oxidation of [(Mo III ) 2 (μ 2 ‐S) 2 (CN) 8 ] 6⊖ . The Mo III/IV species in 1 belongs to the rare paramagnetic binuclear complexes of the heavy transition metals; the Mo IV species is diamagnetic. Although the structures of the two complex anions differ only slightly, markedly different MoMo distances of 279.0 and 268.4 pm, respectively, are observed. equation image

References

2

Magnetic and electrochemical properties of transition metal complexes with multiple metal-to-metal bonds. III. Characterization of tetrapotassium and tripotassium tetrasulfatodimolybdates

F. Albert Cotton, B. A. Frenz, Erik B. Pedersen · Inorganic Chemistry · 1975 · 60 citations

, , +17

Reaction between Molybdate(<scp>VI</scp>), Cyanide, and Hydrogen Sulfide

Michael G. B. Drew, Philip C. H. Mitchell, Christopher F. Pygall · Angewandte Chemie International Edition in English · 1976 · 34 citations

, , +4