Concepedia

Suzuki–Miyaura coupling reactions in aqueous microdroplets with catalytically active fluorous interfaces

Ashleigh B. Theberge, Graeme Whyte, Max Frenzel, Luis M. Fidalgo, Robert C. R. Wootton, Wilhelm T. S. Huck

Chemical Communications · 2009 · 69 citations · 25 references

DOI

Concepts

Abstract

Using microfluidic techniques and a novel fluorous-tagged palladium catalyst, we generated droplet reactors with catalytically active walls and used these compartments for small molecule synthesis.

References

25

A new stereospecific cross-coupling by the palladium-catalyzed reaction of 1-alkenylboranes with 1-alkenyl or 1-alkynyl halides

Norio Miyaura, Kinji Yamada, Akira Suzuki · Tetrahedron Letters · 1979 · 2.2K citations

, , +9

Dynamic Pattern Formation in a Vesicle-Generating Microfluidic Device

Todd Thorsen, Richard W. Roberts, Frances H. Arnold et al. · Physical Review Letters · 2001 · 2K citations · Full text

, , +18

Facile Catalyst Separation Without Water: Fluorous Biphase Hydroformylation of Olefins

István T. Horváth, József Rábai · Science · 1994 · 1.4K citations

, , +11

A Microfluidic System for Controlling Reaction Networks in Time

Helen Song, Joshua D. Tice, Rustem F. Ismagilov · Angewandte Chemie International Edition · 2003 · 1.1K citations

, , +18

Fluorous Biphase Chemistry

István T. Horváth · Accounts of Chemical Research · 1998 · 737 citations

, , +11