Concepedia

Switchable π-coordination and C–H metallation in small-cavity macrocyclic uranium and thorium complexes

Polly L. Arnold, Joy H. Farnaby, Rebecca C. White, Nikolas Kaltsoyannis, Michael G. Gardiner, Jason B. Love

Chemical Science · 2013 · 61 citations · 62 references

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Concepts

Abstract

Actinide complexes of a small-cavity, dipyrrolide macrocycle exhibit unusual bent metallocene-type binding, or bis(arene)-type binding, or both at once in a di-uranium adduct.

References

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Agostic interactions in transition metal compounds

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Arene-Bridged Diuranium Complexes:  Inverted Sandwiches Supported by δ Backbonding

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Small Molecule Activation by Uranium Tris(aryloxides): Experimental and Computational Studies of Binding of N<sub>2</sub>, Coupling of CO, and Deoxygenation Insertion of CO<sub>2</sub>under Ambient Conditions

Stephen M. Mansell, Nikolas Kaltsoyannis, Polly L. Arnold · Journal of the American Chemical Society · 2011 · 242 citations · Full text

, , +14