Novel, Spongelike Ruthenium Particles of Controllable Size Stabilized Only by Organic Solvents

Abstract

Soluble ruthenium nanoparticles of uniform size (see picture) with a porous spongelike structure were obtained by the reaction of [Ru(C(8)H(10))(C(8)H(12))] with H(2) in methanol or THF/methanol. The particle size can be controlled in the range 15-100 nm by varying the MeOH/THF ratio. The particles catalyze benzene hydrogenation without modification of their size or structure. Their formation is proposed to occur in the droplets of a nanosized emulsion, which act as nanoreactors.