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[(Cp<sup>**</sup>CoH)<sub>2</sub>‐μ‐{η<sup>2</sup>:η<sup>2</sup>‐<i>cis</i>‐μ‐[(C<sub>2</sub>H<sub>5</sub>)<sub>2</sub>Al–CH = CH–Al(C<sub>2</sub>H<sub>5</sub>)<sub>2</sub>]}] and [{Cp<sup>*</sup>(η<sup>2</sup>‐C<sub>2</sub>H<sub>4</sub>)CoAl(C<sub>2</sub>H<sub>5</sub>)}<sub>2</sub>]: Synthesis and Structure of Unusual Co–Al Cluster Compounds
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Citations
29
References
1995
Year
Materials ScienceInorganic ChemistryEngineeringCoordination ComplexCluster ChemistryOrganometallic CatalysisCatalysisMain Group ChemistryChemistryCo–al Clusters 1Inorganic SynthesisCc Unitη2-Bridged Dialumin-ioethene ClustersInorganic Compound
How many metal atoms can coordinate to a CC unit? The answer for Co–Al clusters 1 (R = Me) and 2 (R = Et), the first η-η2:η2-bridged dialumin-ioethene clusters, is “four”. The complexes are formed in about 30% yield on treatment of [Cp+(η2-ethene)2Co] (Cp+ = C5Me5, C5Me4Et) with AlEt2H.
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