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Stepwise construction of grid-type Cu(ii)–Cd(ii) heterometallic MOFs based on an imidazole-appended dipyrrin ligand
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2012
Year
Materials ScienceInorganic ChemistryInorganic CompoundEngineeringCoordination ComplexLinear MetallatectonStepwise ConstructionParallel StackingChemistryGrid-type MofsMetal-organic PolyhedronGrid-type CuCrystallographyInorganic SynthesisBiophysicsImidazole-appended Dipyrrin Ligand
An imidazole-appended dipyrrin ligand yields, upon coordination to Cu(II) cations, a linear metallatecton that self-assembles with Cd(II) salts to afford 2D grid-type MOFs which, upon parallel stacking, lead to porous crystals offering 1D channels.
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