Concepedia

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On the Resolution of Secondary Phosphine Oxides via Diastereomeric Complex Formation: The Case of tert-Butylphenylphosphine Oxide

DOI

13

Citations

0

References

2009

Year

K. Michał Pietrusiewicz, Adriaan J. Minnaard, Jarle Holt, Anna M. Maj, Ebe P. Schudde, Wanda Wieczorek, Thomas Jerphagnon, Isabel W. C. E. Arends, Ulf Hanefeld
Synthesis

Abstract

The secondary phosphine oxide, t-BuPhHP=O most prominent chiral member of this compound class, has been re solved in high yield and with excellent ee. This resolution discloses ail efficient route to enantiopure phosphorus compounds.