Publication | Open Access
Cu<sup>I</sup>‐Catalyzed <sup>11</sup>C Carboxylation of Boronic Acid Esters: A Rapid and Convenient Entry to <sup>11</sup>C‐Labeled Carboxylic Acids, Esters, and Amides
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Citations
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References
2012
Year
Asymmetric CatalysisEngineeringFunctional GroupsOrganic ChemistryOrganometallic CatalysisCatalysisStereoselective SynthesisBoronic Acid EstersChemistryConvenient EntrySynthetic ChemistryEnantioselective SynthesisBiomolecular Engineering
Rapid and direct: the carboxylation of boronic acid esters with (11)CO(2) provides [(11)C]carboxylic acids as a convenient entry into [(11)C]esters and [(11)C]amides. This conversion of boronates is tolerant to diverse functional groups (e.g., halo, nitro, or carbonyl).
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