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Structure and magnetic properties of a high-spin Mn6IICrIII cluster containing cyano bridges and Mn centres capped by pentadentate ligands
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Citations
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References
2001
Year
Magnetic PropertiesEngineeringHigh-spin Mn6iicriii ClusterMagnetic ResonanceChemistryHeptanuclear CationsLinear Chain CompoundInorganic CompoundMagnetismElaborate H-bonding NetworkMaterials ScienceInorganic ChemistryPhysicsChemical BondMn CentresHexacyanochromate Counterions ResultsCyano BridgesCrystallographySpintronicsMolecule-based MagnetNatural SciencesCoordination ComplexCluster ChemistryMolecular ComplexMetal Chain Compound
The formation of an elaborate H-bonding network between heptanuclear cations, consisting of a hexacyanochromate capped by six [Mn(dmptacn)]2+ moieties, and hexacyanochromate counterions results in the assembly of novel 1-D chains with short-range ferrimagnetic behaviour occurring between the S = 27/2 clusters and S = 3/2 ions.
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