Publication | Closed Access
The Role of Secondary Interactions in the Asymmetric Palladium‐Catalysed Hydrosilylation of Olefins with Monophosphane Ligands
90
Citations
45
References
2007
Year
Cross-coupling ReactionSecondary InteractionsEngineeringMonophosphane LigandsOrganic ChemistryOrganometallic CatalysisCatalysisHydrosilylation ReactionChemistryAsymmetric CatalysisBiomolecular Engineering
Abstract A structure‐activity survey of monophosphane ligands used in the asymmetric palladium‐catalysed hydrosilylation reaction of olefins is presented and used to assess the role of secondary interactions on catalyst activity and selectivity.
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