Concepedia

Ir-Catalyzed Preparation of SF<sub>5</sub>-Substituted Potassium Aryl Trifluoroborates via C–H Borylation and Their Application in the Suzuki–Miyaura Reaction

Adrien Joliton, Erick M. Carreira

Organic Letters · 2013 · 48 citations · 32 references

DOI

Concepts

Abstract

The preparation of new pentafluorosulfanyl-substituted potassium aryltrifluoroborates via Ir-catalyzed C-H borylation is reported. The utility of these novel building blocks was demonstrated in the Suzuki-Miyaura cross-coupling reaction, giving access to 3,5-disubstituted pentafluorosulfanylbenzenes.

References

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