Publication | Closed Access
Hybrid Molecular Dumbbells: Bridging Polyoxometalate Clusters with an Organic π-Conjugated Rod
105
Citations
16
References
2002
Year
Supramolecular AssemblyEngineeringBridging Polyoxometalate ClustersOrganic ChemistryBiomedical EngineeringChemistryPolymersHybrid MaterialsBiophysicsπ ElectronsPolymer ChemistryCross-coupling ReactionOrganic π-Conjugated RodMolecular EngineeringMacromolecular ArchitectureOrganometallic PolymerBiomolecular EngineeringSelf-assemblyHybrid Molecular DumbbellsConjugated Organic BridgeStrong Electronic Interactions
Strong electronic interactions occur between the polyoxometalate (POM) clusters and the π electrons of the conjugated organic bridge in hybrid molecular dumbbells such as 1 which were synthesized by Pd-catalyzed coupling reactions of organoimido-substituted POMs.
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