Phosphorverbindungen ungewöhnlicher Koordination, 17¹⁾ über die Abfangreaktion von Phenylthioxophosphan mit Hexacarbonylbis(cyclopentadienyl)dimolybdän

Abstract

Phosphorus compounds with Unusual Cooradination, 17 1) . – On the Trapping Reaction Of Phenylthioxophosphane with Hexacarbonylbnis(cyclopentadienyl)dimolybdenum Phenylthioxophosphane ( 6 ) – generated in boiling toluene from endo/exo ‐ 10 – reacts under these conditions with hexacarbonylbis(cyclopentadienyl)dimolybdenum ( 12 ) to yield the two binuclear molybdenum complexes 13a and 14a . A crystal structural analysis has been performed for 13a . Lawesson's reagent ( 17 ) leads under the same conditions with 12 to the analogous complexes 13b and 14b .