Twelve‐Connected Net with Face‐Centered Cubic Topology: A Coordination Polymer Based on [Cu₁₂(μ₄‐SCH₃)₆]⁶⁺ Clusters and CN⁻ Linkers

Abstract

Globular configuration: a microporous coordination polymer based on a dodecanuclear copper(I) cluster (picture: C black, Cu red, N blue, S yellow) as a twelve-connected node, was synthesized by a simultaneous redox, sulfurization, and self-assembly reaction under solvothermal conditions. The synthesis provides a model reaction to simulate the transformation of inorganic sulfur into organic sulfur. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2005/z500290_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.