Asymmetric Michael reaction. Deracemization of enolate by chiral crown ether

Chiral crown complexes catalyse Michael addition reactions to give adducts in high optical yields

Donald J. Cram, G. D. Y. SOGAH · Journal of the Chemical Society Chemical Communications · 1981 · 200 citations

Natural Sciences, Chemistry, Catalysis +5

Deracemization of Cyclic Allyl Esters

Barry M. Trost, Michael G. Organ · Journal of the American Chemical Society · 1994 · 110 citations

Natural Sciences, Chemistry, Analytical Chemistry +5

Simple chiral crown ethers complexed with potassium tert-butoxide as efficient catalysts for asymmetric Michael additions

Shin Aoki, Shigeki Sasaki, Kenji Koga · Tetrahedron Letters · 1989 · 67 citations

Natural Sciences, Chemistry, Catalysis +11

Deracemization via Highly Enantioselective Enolate Protonation Using a Chiral Aniline as the "Acid"

Edwin Vedējs, Namkyu Lee, S. Sakata · Journal of the American Chemical Society · 1994 · 61 citations

Natural Sciences, Chemistry, Analytical Chemistry +5

Synthesis, complexing properties and applications in asymmetric synthesis of bis--18-crown-6 compounds

M. ALONSO‐LOPEZ, Jesús Jiménez‐Barbero, Manuel Martín‐Lomas et al. · Tetrahedron · 1988 · 47 citations

Natural Sciences, Chemistry, Medicinal Chemistry +13