Design, Synthesis, and Properties of Molecule‐Based Assemblies with Large Second‐Order Optical Nonlinearities

TLDR

The design, synthesis, and characterization of molecular assemblies with large macroscopic optical nonlinearities is an active interdisciplinary field focused on creating functional photonic materials through engineered supramolecular interactions. This review surveys approaches to the microstructural and optical properties of second‑order nonlinear optical materials constructed from noncentrosymmetric chromophore assemblies with large hyperpolarizabilities. The discussed systems include chromophore macromolecule guest‑host matrices, chromophore‑functionalized glassy macromolecules, thermally cross‑linked chromophore‑macromolecule matrices, and intrinsically acentric self‑assembled chromophoric superlattices. These materials efficiently double the frequency of incident light, exhibit other second‑order nonlinear effects, and advance the knowledge base for future photonic device technologies.

Abstract

Abstract The design, synthesis, characterization, and understanding of new molecular and macromolecular assemblies with large macroscopic optical nonlinearities represents an active field of research at the interface of modern chemistry, physics, and materials science. Challenges in this area of photonic materials typify an important theme in contemporary chemistry: to create new types of functional materials by the rational construction of supramolecular assemblies exhibiting preordained collective phenomena by virtue of “engineered” molecule–molecule interactions and spatial relationships. This review surveys several approaches to, and the microstructural and optical properties of, second‐order nonlinear optical materials built from noncentrosymmetric assemblies of chromophores having large molecular hyperpolarizabilities. Such types of materials can efficiently double the frequency of incident light, exhibit other second‐order nonlinear optical effects, and contribute to the knowledge base needed for new photonic device technologies. Systems described include chromophore macromolecule guesthost matrices, chromophore‐functionalized glassy macromolecules, thermally crosslinked chromophore‐macromolecule matrices, and intrinsically acentric self‐assembled chromophoric superlattices.