Concepedia

Highly Active Nickel Catalysts for the Isomerization of Unactivated Vinyl Cyclopropanes to Cyclopentenes

Gang Zuo, Janis Louie

Angewandte Chemie International Edition · 2004 · 143 citations · 36 references

DOI

Concepts

Abstract

Inflatable rings: Low-valent Ni0–nitrogen-heterocyclic carbene catalysts were found to isomerize activated and unactivated vinyl cyclopropanes to their respective substituted cyclopentenes under mild conditions and in high yields (see scheme, cod=cycloocta-1,5-diene).

References

36

Palladium−Imidazol-2-ylidene Complexes as Catalysts for Facile and Efficient Suzuki Cross-Coupling Reactions of Aryl Chlorides with Arylboronic Acids

Chunming Zhang, Jinkun Huang, Mark L. Trudell et al. · The Journal of Organic Chemistry · 1999 · 447 citations

, , +9

Efficient Cross-Coupling of Aryl Chlorides with Aryl Grignard Reagents (Kumada Reaction) Mediated by a Palladium/Imidazolium Chloride System

Jinkun Huang, Steven P. Nolan · Journal of the American Chemical Society · 1999 · 362 citations

, , +12

High Turnover Number and Rapid, Room-Temperature Amination of Chloroarenes Using Saturated Carbene Ligands

Shaun R. Stauffer, Sunwoo Lee, James P. Stambuli et al. · Organic Letters · 2000 · 314 citations

, , +13

General and Efficient Catalytic Amination of Aryl Chlorides Using a Palladium/Bulky Nucleophilic Carbene System

Jinkun Huang, Gabriella A. Grasa, Steven P. Nolan · Organic Letters · 1999 · 241 citations

, , +11

Relative Hydride, Proton, and Hydrogen Atom Transfer Abilities of [HM(diphosphine)<sub>2</sub>]PF<sub>6</sub>Complexes (M = Pt, Ni)

Douglas E. Berning, B.C. Noll, Daniel L. DuBois · Journal of the American Chemical Society · 1999 · 225 citations

, , +16