Supramolecular Coordination Assemblies of Dinuclear Fe^III Complexes

Abstract

Emptying the honeycomb: Hybrid organic–inorganic coordination assemblies are synthesized using modified aminocarboxylic acid ligands as the structure-directing agents. The structure of the networks varies ranging from a lamellar motif through a densely packed hexagonal array, to an open-framework hexagonal assembly (see structure).