Concepedia

Titanium‐Promoted Dinitrogen Cleavage, Partial Hydrogenation, and Silylation

G.B. Nikiforov, I. Vidyaratne, Sandro Gambarotta, Ilia Korobkov

Angewandte Chemie International Edition · 2009 · 83 citations · 100 references

DOI

Concepts

Abstract

Breaking up: Reduction of a trivalent titanium complex afforded NN cleavage with formation of TiIV nitride complexes (see structure), which can be converted into silylated derivatives.

References

100

Interaction of hydrogen with metal nitrides and imides

Ping Chen, Zhitao Xiong, Jizhong Luo et al. · Nature · 2002 · 1.6K citations

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Catalytic Reduction of Dinitrogen to Ammonia at a Single Molybdenum Center

Dmitry V. Yandulov, Richard R. Schrock · Science · 2003 · 1.4K citations

, , +11

Hydrogenation and cleavage of dinitrogen to ammonia with a zirconium complex

J.A. Pool, Emil B. Lobkovsky, Paul J. Chirik · Nature · 2004 · 633 citations

, , +5

Dinitrogen Cleavage by a Three-Coordinate Molybdenum(III) Complex

Catalina E. Laplaza, Christopher C. Cummins · Science · 1995 · 629 citations

, , +7

Catalytic Reduction of Dinitrogen to Ammonia at a Single Molybdenum Center

Richard R. Schrock · Accounts of Chemical Research · 2005 · 495 citations · Full text

, , +11